Highlighted Publications

Journal Articles

Before Michigan State

17. Breaking Barriers in Chalcogenide Perovskite Synthesis: A Generalized Framework for BaMS3 (M = Zr, Hf) Perovskites
S. Agarwal, K. C. Vincent, J. W. Turnley, D. C. Hayes, M. C. Uible, I. Durán, A. S. M. Canizales, S. Khandelwal, I. Panicker, Z. Andoh, R. M. Spilker, Q. Ma, L. Huang, S. Hwang, K. Kisslinger, S. Svatek, E. Antolin, S. C. Bart, R. Agrawal*
Advanced Functonal Materials (2024)

16. Emergence of Ruddlesden-Popper Phases and Other Pitfalls for Moderate Temperature Solution Deposited Chalcogenide Perovskites
A. A. Pradhan, S. Agarwal, K. C. Vincent, D. Hayes, J. M. Peterson, J. W. Turnley, R. M. Spilker, M. C. Uible, S. C. Bart, L. Huang, K. Kisslinger, R. Agrawal*
Materials Chemistry Frontiers (2024)

15. Rethinking tolerance factor analysis for chalcogenide perovskites
J. W. Turnley, S. Agarwal, R. Agrawal*
Materials Horizons (2024)

14. The Viability of Photovoltaics on Agricultural Land: Can PV Solve the Food vs Fuel Debate?
J. W. Turnley*, A. Grant, V. Z. Schull, D. Cammarano, J. Sesmero*, R. Agrawal*
Journal of Cleaner Production (2024)

13. Formation of Homoleptic Zirconium and Hafnium Dithiocarbamates via Insertion of CS2: Breaking Bonds and Taking Names
M. C. Uible, B. S. Prokop, D. C. Hayes, S. Chaudhuri, K. C. Vincent, A. A. Pradhan, A. Rounds, J. W. Turnley, S. Agarwal, R. N. Swope, G. C. Schatz, R. Agrawal, S. C. Bart*
Organometallics (2024)

12. Solution Processed Metal Chalcogenide Semiconductors for Thin Film Photovoltaics
J. W. Turnley and R. Agrawal*
ChemComm (2024)

11. Novel Synthesis of Semiconductor Chalcohalide Anti-Perovskites by Low-Temperature Molecular Precursor Ink Deposition Methodologies
I. Caño*, J. W. Turnley, P. Benítez, C. López-Álvarez, J.-M. Asensi, D. Payno, J. Puigdollers, M. Placidi, C. Cazorla, R. Agrawal, E. Saucedo
Journal of Materials Chemistry C (2024)

10. A Molecular Precursor Approach to Sulfur-Free CuInSe2: Replacing Thiol Coordination in Soluble Metal Complexes
J. W. Turnley, S. D. Deshmukh, V. M. Boulos, R. G. Ellis, N. J. LiBretto, J. K.-Y. Liu, J. T. Miller, H. I. Kenttämaa, R. Agrawal*
ACS Omega (2023)

9. Moderate Temperature Sulfurization and Selenization of Highly Stable Metal Oxides: An Opportunity for Chalcogenide Perovskites
S. Agarwal†, J. W. Turnley†, A. A. Pradhan, R. Agrawal
Journal of Materials Chemistry C (2023)

8. A Selenium-Based “Alkahest”: Reactive Dissolution of Metals and Metal Compounds with Alkylammonium Polyselenide Solutions
J. W. Turnley, S. D. Deshmukh, V. M. Boulos, R. Spilker, C. J. Breckner, K. Ng, J. K.-Y. Liu, J. T. Miller, H. I. Kenttämaa, R. Agrawal*
Inorganic Chemistry Frontiers (2023)

7. Synthesis of BaZrS3 and BaHfS3 Chalcogenide Perovskite Films Using Single-Phase Molecular Precursors at Moderate Temperatures
A. A. Pradhan, M. C. Uible, S. Agarwal, J. W. Turnley, S. Khandelwal, J. M. Peterson, D. D. Blach, R. N. Swope, L. Huang, S. C. Bart*, R. Agrawal*
Angewandte Chemie International Edition (2023)

6. Liquid Flux Assisted Mechanism for Modest Temperature Synthesis of Large-Grain BaZrS3 and BaHfS3 Chalcogenide Perovskites
K. C. Vincent, S. Agarwal, J. W. Turnley, R. Agrawal*
Advanced Energy and Sustainability Research (2023)

5. Amine-Thiol/Selenol Chemistry for Efficient and Stable Perovskite Solar Cells
B. P. Finkenauer, Y. Zhang, K. Ma, J. W. Turnley, J. Schulz, M. Gómez, A. H. Coffey, D. Sun, J. Sun, R. Agrawal, L. Huang, L. Dou*
The Journal of Physical Chemistry C (2023)

4. Solution Deposition for Chalcogenide Perovskites: A Low-Temperature Route to BaMS3 Materials (M = Ti, Zr, Hf)
J. W. Turnley, K. C. Vincent, A. A. Pradhan, I. Panicker, R. Swope, M. C. Uible, S. C. Bart, R. Agrawal*
Journal of the American Chemical Society (2022)

3. Direct Synthesis of Sulfide-Capped Nanoparticles for Carbon-Free Solution-Processed Photovoltaics
R. G. Ellis, S. D. Deshmukh, J. W. Turnley, D. S. Sutandar, J. P. Fields, R. Agrawal*
ACS Applied Nano Materials (2021)

2. Hybrid Ligand Exchange of Cu(In,Ga)S2 Nanoparticles for Carbon Impurity Removal in Solution-Processed Photovoltaics
R. G. Ellis, J. W. Turnley, D. J. Rokke, J. P. Fields, E. H. Alruqobah, S. D. Deshmukh, K. Kisslinger, R. Agrawal*
Chemistry of Materials (2020)

1. Expoliated Transition Metal Dichalcogenide Nanosheets for Supercapacitor and Sodium Ion Battery Applications
S. Mukherjee, J. Turnley, E. Mansfield, J. Holm, D. Soares, L. David, G. Singh*
Royal Society Open Science 6 (2019)

*Corresponding Author, †Equal Contribution, Mentored Student

Patents

2. R. Agrawal, A. A. Prahdah, J. W. Turnley, S. C. Bart, M. C. Uible, “Chalcogenide perovskites and method for synthesizing chalcogenide perovskites” US20230322576A1

1. R. Agrawal, J. W. Turnley, S. D. Deshmukh, “Direct solution deposition of metal selenide semiconductors using novel metal-selenium complexes and films made therefrom” US20240327218A1